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شہیدعلی محمد ہنگورو

شہید ابن شہید علی محمد ہنگورو

لیاری کی تنگ و تاریک گلیوں میں جنم لینے والا علی محمد ہنگورو بالمعروف ’’علی ہنگورو ‘‘نسل در نسل باوقار جد وجہد سے جام شہادت تک ثابت قدم ،شہید علی ہنگورو کے والد شہید یعقوب ایک مزدور لیڈر تھے ۔

وہ مچھی میانی میں مزدور کاز کا دفاع کرتے ہوئے اپنی جان کی بازی ہار گئے ۔باپ کی شہادت نے کم سن علی ہنگورو پر گہرے نقش چھوڑے غربت پروری اور وفاداری والد سے حصے میں ملی

شہید علی محمد ہنگورو کی زندگی مزدوری سے سندھ اسمبلی نشست تک ان تھک جدو جہد سے پُر ہے اپنی جد وجہد کا آغاز پیپلز اسٹوڈنٹس فیڈریشن اور بعد ازاں سندھ پیپلز یوتھ سے کیا ،وہ جد وجہد پر یقین رکھتا تھا ۔

اپنی اسی روشن خیالی کی بدولت سازشوں ،بہروپیوں اور بھٹو دشمن عناصر قوتوں کو کھٹکتا تھا ،اس نے اپنے وقت کے آمر جام صادق کو للکارا اور اسمبلی کے فلور پر نعرہ حق بلند کیا ۔

یا الہی کسی کم ظرف کو طاقت نہ ملے

کسی ظالم کو زمانے کی قیادت نہ ملے

فکر منفی کو کبھی علم و فراست نہ ملے

اور جب سازشیں حد سے بڑھیں زرداروں کا عمل دخل اور غریب ورکروں کے ساتھ زیادتیاں بڑھنے لگیں علی سید مظفر حسین شاہ کے دور میں آزاد سیٹ پر بیٹھ کر اپنی جدوجہد جاری رکھی ۔

1993ء میں جب میر مرتضی بھٹو کے وطن واپسی پر اعلان کے ساتھ علی شہید نے شہید بھٹو کمیٹی بنا کر میر مرتضی بھٹو کا استقبال کیا پھر نہ رات دیکھی نہ دن لیاری کا یہ کمانڈر استقبال تیاریوں میں مصروف ہو گیا وہ تاریخ...

Attitude Towards Science: A Case Study of Higher Secondary Level Students of Sindh Province

This research is conducted, in order to perceive the attitude of higher secondary level students of Sindh towards science. Students (Male = 448, Female = 648) belonging to higher-secondary level (Class-XI & XII) from Hyderabad division were surveyed. Students were divided in Urban (N=455) and Rural (N=641) groups accordingly. “Test of Science Related Attitudes” known as TOSRA, initially developed by (Fraser, 1978) was adapted and translated in Urdu as well, was used as the attitude measurement instrument. Internalk consistancey was checked with Cronbach’s alpha reliability test. After pilot study the test was administrated. Significant difference of the attitude towards science across the students was noticed based on their gender and their locale. The results show that, with small effect size, male students significantly scored higher on almost all of the attitude sub-scales of TOSRA as compared to female students. Interestingly, students belonging to rural areas significantly scored higher with medium effect size on all the attitude sub-scale towards science as compare to students from urban areas.

Thermal and Catalytic Degradation of High-Density Polyethylene for Energy Recovery and Quality Environment

Polymers wastes create great environmental problems in different ways and therefore should be properly disposed. To convert these waste polymers to other useful products like feedstock chemicals and fuel is a promising solution to these problems. The objective of this work is to develop environmental friendly methods for the degradation of Highdensity polyethylene (HDPE) into useful products which could be directly or indirectly used as chemicals or fuel. The first chapter of this dissertation is concerned about a brief introduction of different types of polymers. It includes history and classification of polymers and information regarding the types, formulas, structures and characteristic of different types of polymers. Different types of polyethylenes have been discussed in this chapter. It focuses specifically on HDPE and its different preparation methods have been included in this chapter. It also describes properties and applications of polyethylene (PE), more specifically HDPE. Several degradation methods and mechanistic aspects of the degradation processes have been discussed. The second chapter covers a thorough review of the recent and relevant literature reported for the thermal and thermocatalytic degradation of PE and HDPE. Chapter III consists of experimental methods applied for thermal and catalytic conversion of HDPE. Different equipments used in the study and experimental procedures have been discussed. Indigenous batch reactor and furnace consisting of IR heating elements were used for the catalytic and thermal pyrolysis of HDPE. The liquid products were fractionated and the fractions were analyzed by GC and GC/MS. Different physical parameters for the oil products were studied. Chapter IV is concerned with results and discussion about the experimental findings. For maximum conversion into oil products, conditions like temperature, catalyst weight and reaction time and nitrogen flow rate were optimized. Several catalysts like MgCO3, CaCO3, BaCO3, Ultra stable Y-zeolite (US-Y), were applied for the catalytic degradation of HDPE. Different temperatures like 250oC, 300oC, 350oC, 395oC, 400oC, 410oC, 420oC, 430oC, 440oC, 450oC, 460oC and 480oC were explored in order to find out the optimum reaction temperature for thermal and catalytic degradation process of HDPE. From the catalytic degradation of HDPE using these catalysts, it was found that among the carbonates, MgCO3 and CaCO3 were approximately effective up to an equal extent in terms of total conversion (96.80% and 97.20% respectively) and oil yield (51.87% and 52.33% respectively) but the temperature for the later catalyst was 460°C and for the former it was 450°C. Reaction time and cat/pol ratio in both the cases were same (1.5 h). In case of BaCO3 catalyst the total conversion (96.07%) was comparable with total conversion achieved with MgCO3 and CaCO3 but the liquid yield (41.33%) was considerably low. Among the applied zeolite catalysts, the powdered US-Y was found to be the most efficient catalyst for the degradation of HDPE. With US-Y catalyst, a total percent conversion of 96.70% was achieved in a 25min experiment with nitrogen flow rate of 10mL/min and a cat/pol ratio of 1:8 at a very low reaction temperature of 395°C. The % oil yield in this case was 71.45%. Under the same experimental conditions but at a higher temperature (420°C), the total % conversion achieved was 96.34% with a little increase in the % oil yield (72.13%). The liquid products obtained thermally and catalytically in bulk quantities were fractionated at different temperatures like100°C, 150°C, 200°C, 250°C and 300°C. The parent liquid products and the fractions collected at different temperatures were characterized by physicochemical tests. The physical parameters like refractive index, density, specific gravity, API gravity, viscosity, kinematic viscosity, flash point, calorific value and ASTM distillation were determined according to IP and ASTM standard methods for fuel values. From the physical tests, it was observed that the results for the liquid fractions were somehow comparable with the standard values for gasoline, kerosene and diesel oil. All the fractions and parent liquids were analyzed by GC and on the basis of boiling point distribution (BPD), the composition of samples was investigated. GC/MS analysis of these samples was also conducted in order to determine the exact composition of thermally and catalytically derived liquids. With increasing distillation temperature, a gradual increase in the percentage of heavier hydrocarbons was observed. It could be concluded, that catalytic degradation of HDPE yields valuable products in terms of fuel oils and chemical feedstocks on one hand and could be a best solution to environmental problems caused by HDPE on the other hand. However more efforts are required to apply this catalytic degradation process for the proper disposal of waste HDPE on industrial scale.
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