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ہم سے درویش کوئی مال نہ زر رکھتے ہیں
ہم سے درویش کوئی مال نہ زر رکھتے ہیں
کوئی دیوار نہ در اور نہ گھر رکھتے ہیں
یہ بھی سچ ہے کہ نہ ہم بال، نہ پر رکھتے ہیں
جاری ہم پھر بھی وفائوں کا سفر رکھتے ہیں
رکھتے بے تاب ہیں دل، آنکھ کو تر رکھتے ہیں
مرے حالات مجھے زیر و زبر رکھتے ہیں
چاکِ دامان لیے خاک بسر رہتے ہیں
تیرے دیوانے کہاں اپنی خبر رکھتے ہیں
اُن کے تُو میرے خدا! خیر سے سینے بھر دے
میرے احباب کہ جو سینوں میں شر رکھتے ہیں
روٹھنے والے بھلا بیٹھے ہیں تائب ؔہم کو
روٹھنے والوں کو ہم یاد مگر رکھتے ہیں
Impact Analysis of Higher Education Research Trajectory on Governance and Public Policy: A Case Study of Four Federal Universities of Pakistan
The research situates link between the graduate researches in four academic institutes of Islamabad and analyzes its impact on the public policy. The study explores the relevance of graduate research trajectory followed by various academic departments of four major federal universities in Pakistan in formulation and execution of public policy. The author collected last five years graduate level dissertation titles from four federal universities and classified them by using thematic approach. An interview guide/questionnaire is prepared accordingly. Chairpersons, deans, professors, bureaucrats, and parliamentarians were approached for semi-structured, in-depth interviews. This is a qualitative study using thematic and analytical approach. The research finds a lack of cohesion between the graduate research trajectory and policy needs of the public institutions. The absence of a national research vision and collaborative framework, difference in training cultures of bureaucracy and academia, lack of logistic support system, defective learning strategies, and an overall neglect for social sciences are the major reasons for incoherence. The analytical correlation of the recorded opinions reveals opportunities to maximize the relevance of the academic research in public policy domainOrganotin Iv Complexes With O’O Donor Atoms from Carboxylic Acid Derivatives
In the present study, a series of tri- and diorganotin(IV) carboxylates have been synthe sized by the reaction of tri- and diorganotin(IV) chlorides/oxides with substituted phenylethanoic acids/salts and α-alkyl cinnamic acids/salts in dry toluene under reflux condition for 8-10 h. The ligands used were 4-Methoxyphenylethanoic acid (HL 1 ), 4- Nitrophenylethanoic acid (HL 2 ), 4-Chlorophenylethanoic acid (HL 3 ), 3-Methylphenyl ethanoic acid (HL 4 ), 3-(4-Bromophenyl)-2-ethylacrylic acid (HL 5 ), 3-(4-Bromophenyl) -2-methylacrylic acid (HL 6 ), 3-(4-Chlorophenyl)-2-methylacrylic acid (HL 7 ), 3-(4- Chlorophenyl)-2-ethylacrylic acid (HL 8 ), 3-(4-Nitrophenyl)-2-methylacrylic acid (HL 9 ) and 3-(4-Nitrophenyl)-2-ethylacrylic acid (HL 10 ). The composition, coordination mode of ligands, structural confirmation and geometry assignment of the complexes in solid and in solution states were made by different analytical techniques such as elemental analysis, FT-IR, multinuclear ( 1 H, 13 C and 119 Sn) NMR, mass spectrometry and X-ray single crystal analysis. Based on these results, the ligand appeared to coordinate the Sn atom via COO moiety. The triorganotin(IV) derivatives demonstrate polymeric trigonal bipyramidal geometry in solid state and a monomeric tetrahedral structure in solution. The diorganotin(IV) dicarboxylates have shown a distorted octahedral or skew- trapezoidal geometry in solid state, however, the coordination around Sn change from six to five in solution, in most cases. The interaction of (n-C 4 H 9 ) 3 Sn(IV)L, (CH 3 ) 3 Sn(IV)L, (n-C 4 H 9 ) 2 (IV)SnL 2 and (C 2 H 5 ) 2 Sn(IV)L 2 (where L = 4-nitrophenylethanoate) with DNA was investigated by cyclic voltammetry (CV). The positive peak potential shift in CV evidenced intercalative mode of interaction of these complexes with DNA. The CV results revealed the following increasing order of binding strength: (C 2 H 5 ) 2 Sn(IV)L 2 (8.5 x 10 3 ) < (n-C 4 H 9 ) 2 Sn(IV)L 2 (1.11 x 10 4 ) < (CH 3 ) 3 Sn(IV)L (1.39 x 10 4 ) < (n- C 4 H 9 ) 3 Sn(IV)L (1.46 x 10 4 ) M -1 . The negative values of ∆G designate the spontaneity of complex-DNA binding. Most of the synthesized complexes were screened for their antibacterial and antifungal activities against various medically important bacteria and fungi. The triorganotin(IV) derivatives have strong bactericidal and fungicidal action than diorganotin(IV) complexes with few exceptions. Some of the compounds were found to have antimicrobial activity comparable or even more than reference drugs and may be used as drugs in future. Some complexes have shown higher cytotoxicity(against iiBrine shrimp) than standard drug while only compound 10 was found stronger anticancer agent against human prostate cell lines(PC-3).Journals by Discipline
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